Product ID:3-HYDROXY-2-BUTANONE, 108979
MSDS Date:07/01/1999
FSC:6810
NIIN:00N092230
Status Code:A
MSDS Number: CJQRH

Emergency Phone: 414-273-3850

Info Phone: 414-273-3850

Cage: 60928

Telephone: 414-273-3850

Cage: 60928

3-HYDROXY-2-BUTANONE

CAS: 513-86-0

RTECS: EL8790000

LD50 LC50 Mixture:LD50: (ORAL,RAT) > GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. VAPOR OR MIST IS IRRITATING TO EYES,
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. CAUSES SKIN
IRRITATION. TO THE BEST OF MANUFACTUR ER'S KNOWLEDGE, THE CHEMICAL,
PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING & SHOES. ASSURE ADEQUATE FLUSHING OF EYES BY
SEPARATING TH E EYELIDS WITH FINGERS. IF INHALED, REMOVE TO FRESH
AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON I S CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED
CLOTHING BEFORE REUSE.

Flash Point:=50.C, 122.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
EYES. COMBUSTIBLE LIQUID.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
FLASH BACK.

Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. WEAR NIOSH
APPRVD RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
RUBBER GLOVES. COVER WITH DRY LIME OR SODA ASH, PICK UP, KEEP IN A
CLOSED CONTAINER AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND
WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:COMBUSTIBLE. IRRITANT. IRRITATING TO
EYES, RESP SYS & SKIN. KEEP AWAY FROM SOURCES OF IGNIT - NO
SMOKING. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES & EYE/FACE
PROTECTION. REFRIGERATE. STORE AWAY FROM HEAT. PROTECT FROM LIGHT.
Other Precautions:AVOID BREATHING VAPOR. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP TIGHTLY
CLOSED. KEEP AWAY FROM HEAT AND OPEN FLAME.

Respiratory Protection:WEAR APPROPRIATE NIOSH-APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

Boiling Pt:=148.C, 298.4F
Spec Gravity:0.997

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. STRONG BASES.
Stability Condition to Avoid:STORE AWAY FROM HEAT AND DIRECT SUNLIGHT.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.

Waste Disposal Methods:THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Toxicological Information:IRRIT DATA: SKN-RBT 500 MG/24H MOD. FCTXAV
17,509,1979. TOX DATA: ORL-RAT LD5:>5 GM/KG. FCTXAV 17,509,1979.
SKN-RBT LD50:>5 GM/KG. FCTXAV 17,509,1979. ONLY SELECTED REGISTRY
OF TOXIC EFFECTS OF CHEMIC AL SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.

Ecological:NOT YET AVAILABLE.

Transport Information:CONTACT ALDRICH CHEMICAL COMPANY FOR
TRANSPORTATION INFORMATION.

Federal Regulatory Information:EUROPEAN INFO: FLAMM. IRRITANT. R
36/37/38. IRRITATING TO EYES, RESPIRATORY SYSTEM & SKIN. FLAMMABLE.
S 16. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. S 26/ IN
CASE OF CONTACT WITH EYES, RINSE I MMED W/PLENTY OF WATER & SEEK
MED ADVICE. S 36/37/39. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES
AND EYE/FACE PROTECTION. REVIEWS, STANDARDS, AND REGULATIONS.
OEL=MAK. EPA TSCA SECTION 8(B) CHEMICAL IN VENTORY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.